martes, 10 de noviembre de 2009

Bienvenidos a mi Blog

Hola todos.
En este Blog podrás conocer las reglas necesarias para nombrar a los compuestos químicos de una forma rápida y sencilla.  Espero que les sea de mucha ayuda.

NOMENCLATURA QUÍMICA
La nomenclatura química  es un conjunto de reglas que se utilizan para nombrar todas aquellas combinaciones que se dan entre los elementos y los compuestos químicos. Actualmente la máxima autoridad en cuanto a la nomenclatura química es la IUPAC (Unión Internacional de Química Pura y Aplicada, en inglés International Union of Pure and Applied Chemistry). Esta entidad se encarga de establecer las reglas a  nivel mundial para dar los nombres a los diferentes compuestos químicos.



FUNCIONES QUÍMICAS


ÓXIDOS

Se define un óxido como la combinación binaria de un elemento con el oxígeno. Con el oxígeno, es corriente que los elementos presenten varios grados de valencia o numero de oxidación, mientras que el O2= siempre es divalente excepto en los peróxidos donde actúa con una valencia de -1. Para saber la valencia o valencias de un elemento cualquiera con O2 y poder formular el correspondiente óxido, basta con observar su ubicación en la tabla periódica, en la cual el número de la columna indica la valencia más elevada que presenta un elemento para con el O. Los óxidos se dividen en dos categorías según sea el tipo del elemento que se combina con el oxígeno .



ÓXIDOS BÁSICOS

Las combinaciones del oxígeno con los metales, se llaman óxidos básicos o simplemente óxidos. El método tradicional para nombrar los óxidos básicos consiste en usar el nombre óxido de seguido de nombre del metal
Ejemplos:
Li2O = óxido de litio
CaO = óxido de calcio


Cuando un metal presenta dos números de oxidación diferentes, para designar el óxido se emplean las terminaciones oso ( para el elemento de menor numero de oxidación) e ico ( para el de mayor numero de oxidación)
Ejemplos:

CoO = óxido cobaltoso
Co2O3 = óxido cobaltico


Para este caso, en el sistema moderno de nomenclatura, recomendado por la IUPAC, el número de oxidación del metal que se combina con el oxígeno se indica con números romanos entre paréntesis agregado al final del nombre del elemento en español:
Ejemplos:
Co2O = óxido de cobalto (II)
Co2O3 = óxido de cobalto (III)


ÓXIDOS ÁCIDOS

Las combinaciones del oxígeno con los elementos no metálicos se llaman óxidos ácidos o anhidros ácidos
Ejemplos:
SiO2 = dióxido de silicio
SeO2 = dióxido de selenio


Estos óxidos reaccionan con el agua para dar ácidos (tipo oxácido)
Ejemplo:
CO2 + H2O → H2CO3 ácido carbónico (oxido ácido u oxácido)


Para nombrar estos compuestos, la IUPAC recomienda el uso de la palabra óxido y los prefijos griegos; mono, di tri, tetra, etc. que indican el numero de átomos de cada clase en la molécula
Ejemplos:
TeO2 = dióxido de telurio
TeO3 = trióxido de telurio
As2O3 = trióxido de diarsenico
As2O5 = pentaóxido de diarsenico
2Cl2 + O2 → Cl2O = monóxido de dicloro (oxido ácido)


Cuando un elemento presenta dos valencias diferentes, se usa la terminación oso para el oxido que tiene el elemento de menor valencia y la terminación ico para el de menor valencia:
Ejemplos:
TeO2 = oxido teluroso
TeO3 = oxido telúrico


Sin embargo, el mejor método y el que ofrece manos confusión es el de la IUPAC o sistema Stock, donde el numero de oxidación o valencia se indica con números romanos entre paréntesis. Para los óxidos de los halógenos todavía se usan los prefijos hipo y per combinados con los sufijos oso e ico.
Ejemplos:
2N2 + 3O2 → 2N2O3 = óxido de nitrógeno (III) (oxido ácido)
2Cl2 + O2 → 2Cl2O = óxido hipocloroso (oxido ácido)
2Cl2 + 7O2 → 2Cl2O7 = óxido perclórico (oxido ácido)


BASES O HIDRÓXIDOS
Se entiende por hidróxido cualquier compuesto que tiene uno o mas iones hidróxido remplazables (OH). Las bases se obtienen por la reacción de los óxidos metálicos con el agua
Ejemplos:
Na2O + H2O → 2NaOH = hidróxido de sodio
Al2O3 + 3H2O → 2Al(OH)3 = hidróxido de aluminio


Como el grupo hidroxilo es monovalente, para formular una base se añade al metal que lo forma, tantos iones OH- como indica la valencia del metal. Las bases se nombran con las palabra hidróxido de seguidas del nombre del metal.


Cuando un elemento presenta dos estados de oxidación diferentes como ya se vio , el nombre termina en oso en los compuestos en que el elemento tiene la menor valencia y en ico en los que el elemento tienen la mayor valencia
Ejemplo:
Ni(OH)2 = hidróxido niqueloso Ni (OH)3 = hidróxido niquelico


ÁCIDOS
Un ácido se puede describir como una sustancia que libera iones hidrogeno (H+) cuando se disuelve en agua: Las formulas de los ácidos contienen uno o mas átomos de hidrogeno, así como un grupo aniónico. Según la definición de Bronsted -Lowry, ácido es toda sustancia capaz de ceder protones,(H+).En las formulas de todos los ácidos el elemento hidrogeno se escribe en primer lugar. Hay dos clases de ácidos: los hidrácidos y los oxácidos.


HIDRÁCIDOS
Que no contienen oxígeno. Son ácidos binarios formados por la combinación del hidrogeno con un elemento no metal. Se nombran empleando la palabra genérica ácido seguida del nombre en latín del elemento no metálico con la terminación hídrico. A los hidrácidos se les considera como los hidruros de los elementos de los grupos Vi y VII.
Ejemplos:
H2S ácido sulfhídrico
HI ácido yodhídrico
HBr ácido bromhídrico
HF ácido fluorhídrico
HCl ácido clorhídrico


OXÁCIDOS
Son ácidos ternarios que resultan de la combinación de un oxido ácido con el agua; por tanto, son combinaciones de hidrógeno, oxigeno y un no metal.
Ejemplos:
PO3 + H2O → H3PO3 = ácido fosforoso
PO4 + H2O → H3PO4 = ácido fosfórico


Los oxácidos se nombran como los anhídridos u óxidos de donde provienen. La fórmula general de los oxácidos u oxácidos es: ( HO)mXOn; donde m es el numero de grupos OH enlazados covalentemente al central X y n es el numero de oxígenos enlazados covalentemente a X


SALES
Una sal es el producto de la reacción entre un ácido y una base: en esta reacción también se produce agua: en términos muy generales, este tipo de reacción se puede escribir como : Base + Ácido → Sal + Agua
Ejemplo:
NaOH + HCl → NaCl + H2O


Se observa que el ácido dona un H+ a cada OH- de la base para formar H2O y segundo que la combinación eléctricamente neutra del ion positivo Na+, de la base y el ion negativo del ácido, Cl-, es lo que constituye la sal. Es importante tener en cuenta que el elemento metálico, Na+, se escribe primero y luego el no metálico, Cl-.


También se considera una sal a el compuesto resultante de sustituir total o parcialmente los hidrógenos ( H+) de un ácido por metales: las sales se dividen en sales neutras, sales haloideas o haluros, oxisales , sales ácidas y sales básicas.


SALES NEUTRAS
Resultan de la sustitución total de los hidrógenos ( H+) por un metal. El nombre que recibe la sal se deriva del ácido del cual procede; las terminaciones cambian según la siguiente tabla ;


NOMBRE DEL ÁCIDO  NOMBRE DE LA SAL
hídrico                               uro
hipo - oso                         hipo - ito
oso                                   ito
ico                                    ato
per  - ico                          per - ato


se da primero el nombre del ion negativo seguido del nombre del ion positivo


FeCl2 = cloruro ferroso FeCl3 = cloruro férrico


Sin embargo para este caso el esquema de nomenclatura de la IUPAC, que se basa en un sistema ideado por A Stock, indica el estado de oxidación del elemento mediante un numero romano en paréntesis a continuación del nombre del elemento así;
Ejemplo:
FeCl2 = cloruro de hierro ( II) FeCl3 = cloruro de hierro (III)
Si el elemento metálico forma un ion de un solo estado de oxidación no se usa numero romano ejemplo;
Ejemplo:
LiI = Yoduro de Litio


SALES HALOIDEAS O HALUROS
Se forman por la combinación de un hidrácido con una base. En la formula se escribe primero el metal y luego el no metal (con la menor valencia) y se intercambian las valencias). Los haluros se nombran cambiando la terminación hidrico del ácido por uro y con los sufijos oso e ico, según la valencia del metal.
Ejemplos:
Cu(OH) + HCl → CuCl + H2O 
     ácido clorhídrico  cloruro cuproso


2Fe(OH)3 + H2S → Fe2S 3 + 6H2O
ácido sulfhídrico          sulfuro férrico


Si un par de no metales forman más de un compuesto binario, como es el caso más frecuente, para designar el número de átomos de cada elemento En este el estado de oxidación del elemento se usan los prefijos griegos: bi: dos, tri: tres, tetra: cuatro, penta: cinco, hexa: seis, etc, antecediendo el nombre del elemento, por ejemplo:
PS3 = trisulfuro de fósforo PS5 = pentasulfuro de fósforo


OXISALES
Las oxisales se forman por la combinación de un oxácido con una base. En la formula se escribe primero el metal, luego el no metal y el oxigeno. Al metal se le coloca como subíndice la valencia del radical (parte del oxácido sin el hidrogeno) que depende del numero de hidrógenos del ácido. Las oxisales se nombran cambiando la terminación oso del ácido porito e ico por ato
Ejemplos:
KOH + HClO        →      KClO + H2O
      ácido hipocloroso        hipoclorito de sodio


Al(OH)3 + HNO3 → Al(NO3)3 + H2O
              ácido nítrico   nitrato de aluminio


SALES ÁCIDAS
Resultan de la sustitución parcial de los hidrógenos del ácido por el metal. en la formula se escribe primero el metal, luego el hidrogeno y después el radical.
Ejemplo:
NaOH + H2CO3 → NaHCO3 + H2O
    ácido carbónico     carbonato ácido de sodio ( Bicarbonato de sodio)


SALES BÁSICAS
Las sales básicas resultan de la sustitución parcial de los hidróxidos (OH) de las bases por no metales. En la formula se escribe primero el metal, luego el OH y finalmente el radical.
Ejemplo:
CuOHNO3 = nitrato básico de cobre (II)


Se aplican las reglas generales para nombra oxisales, pero se coloca la palabra básica entre nombre del radical y el metal
Ejemplo:
Cu(OH)2 + HNO3 → CuOHNO3 + H2O
              ácido nitrico    nitrato básico de cobre (II)


SALES DOBLES
Se obtienen sustituyendo los hidrógenos de ácido por mas de un metal. en la formula se escribe los dos metales en orden de electropositividad y luego el radical. Se da el nombre del radical seguido de los nombres de los metales respectivos.
Ejemplo:
Al(OH)3 + KOH + H2SO4 → KAl(SO4) + H2O
                       ácido sulfúrico    sulfato de aluminio y potasio ( alumbre)


PERÓXIDOS
Los peróxidos resultan de sustituir los dos hidrógenos del agua oxigenada por elementos metálicos. Se nombran con la palabra peróxido seguida del correspondiente metal.
Ejemplo:
Na2O2 = peróxido de sodio Ba2O2 = peróxido de bario


HIDRUROS
La combinación de cualquier elemento con el hidrogeno constituye un hidruro. el hidrogeno es siempre monovalente y en el caso de los hidruros metálicos presenta un estado de oxidación de -1 ( en los demás casos aparece como +1). Para saber la valencia que tiene un elemento cualquiera, al combinarse con el hidrogeno para formar el correspondiente hidruro, basta con observar la tabla periódica y tener en cuenta las siguientes reglas:


1. Los elementos de las tres primeras columnas, presentan con el Hidrogeno la valencia que indica el numero de la columna; así: primera columna= monovalentes, segunda columna= divalentes, tercera columna= trivalentes.
2. Para saber la valencia con el hidrogeno de los elementos de las columnas IV a VIII, se resta de 8 el numero característico de la columna que ocupa el elemento, Así, los elementos de la columna V serán trivalentes porque 8-5 = 3


En cuanto a la nomenclatura, los hidruros formados por los metales reciben el nombre ; Hidruro de ... (nombre del elemento combinado por el H). Los hidruros de los no metales reciben nombres especiales


Ejemplos:
NaH = hidruro de sodio
NH3 = amoniaco
CoH3 = hidruro de cobalto
PH3 = fosfina


OBSERVA EL SIGUIENTE VIDEO



 
CIBERGRAFIA
http://www.cespro.com/Materias/MatContenidos/Contquimica/QUIMICA_INORGANICA/nomenclatura_qca.htm
http://es.wikipedia.org/wiki/Nomenclatura_qu%C3%ADmica
http://www.youtube.com/watch?v=Y4-_t5Jm2rk
























































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